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This achievement is rewarded for completing the first phase of the legendary quest chain to earn your legendary gem.

To earn your gem and this achievement, you will need to complete several quests for Wrathion, who is found in an Inn in the Veiled Stair.  The requirements on the way to your gem include grinding The Black Prince reputation, collecting  Sigil of Wisdom and  Sigil of Power from Tier14 raids, and looting a  Chimera of Fear from the Sha of Fear in  Terrace of Endless Spring. All the raiding steps can be completed on LFR, Normal and/or Heroic. 

The full quest chain for Chapter I is as follows:

It begins with the  Mysterious Note, which is given from several NPCs in Pandaria.  It will direct to you visit Wrathion in the Veiled Stair for the quest Stranger in a Strange Land.  Once there, he will ask you to share a drink with him for the quest A Legend in the Making which gives you some lore background and his story.

Wrathion will then give you two quests to complete:

• The Strength of One's Foes
• Trial of the Black Prince

 Sigil of Power and  Sigil of Wisdom drop in  Mogu'shan Vaults,  Heart of Fear, and  Terrace of Endless Spring on any difficulty level.

The reputation can be farmed from various level 90 mobs out in the world.

After this, you will get the quest Fear Itself which requires you to kill the Sha of Fear in the  Terrace of Endless Spring to get the  Chimera of Fear.  This item can be looted in LFR, Normal or Heroic modes.

Finally, he will ask you to meet just outside the inn to complete Breath of the Black Prince and pick up your new gem and the achievement  Chapter I: Trial of the Black Prince and begin the second chapter.